Synthesis and characterization of a Schiff base derived from 2-aminobenzylamine and its Cu(II) complex: Electropolymerization of the complex on a platinum electrode

DEMETGÜL C., Deletoǧlu D., Karaca F., YALÇINKAYA S., Tmur M., Sern S.

Journal of Coordination Chemistry, cilt.63, sa.12, ss.2181-2191, 2010 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 63 Sayı: 12
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1080/00958972.2010.496852
  • Dergi Adı: Journal of Coordination Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2181-2191
  • Anahtar Kelimeler: 2-Aminobenzylamine, Copper(II) complex, Electropolymerization, Modified electrode, Schiff base
  • Hatay Mustafa Kemal Üniversitesi Adresli: Evet

Özet

A precursor (H3A) was synthesized by the mono condensation of 2-aminobenzylamine with salicylaldehyde and then a tetradentade Schiff-base ligand (H2L) prepared by using H3A and 3-methoxysalicylaldehyde. The copper(II) complex of this new ligand was prepared and characterized by elemental analysis, electronic absorption, Fourier transform infrared (FT-IR), and magnetic susceptibility. For the ligand, 1H- and 13C-NMR and liquid chromatography mass spectrometry (LC-MS) spectra were obtained. The tetradentate ligand is coordinated to Cu(II) through the phenolic oxygen and azomethine nitrogen. The use of this metal complex in the preparation of a modified electrode is also described. CuL was electropolymerized on a platinum electrode surface in a 0.1 mol dm-3 solution of lithium perchlorate in acetonitrile by cyclic voltammetry between 0 and 1.6 V versus Ag/Ag+. Electrochemical properties of the electroactive polymeric film have been investigated and a surface confined polymerization mechanism was proposed. © 2010 Taylor & Francis.