Adsorption of hexavalent chromium from aqueous solutions by bio-chars obtained during biomass pyrolysis


Deveci H., Kar Y.

Journal of Industrial and Engineering Chemistry, vol.19, no.1, pp.190-196, 2013 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 19 Issue: 1
  • Publication Date: 2013
  • Doi Number: 10.1016/j.jiec.2012.08.001
  • Journal Name: Journal of Industrial and Engineering Chemistry
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.190-196
  • Keywords: Adsorption, Bio-char, Hexavalent chromium, Pyrolysis
  • Hatay Mustafa Kemal University Affiliated: Yes

Abstract

In this study, bio-chars were evaluated as a potential adsorbent for the removal of Cr (VI) ions from aqueous solutions. The effects of some important parameters including initial pH (1.5-7), adsorbent dose (0.2-5. g/L), contact time (5-900. min) and initial Cr (VI) ion concentration (5-75. mg/L) were tested on the removal of Cr (VI) ions from aqueous solution in batch experiments. Maximum adsorption capacities of the tested bio-chars under the certain experimental conditions determined as optimal were 3.53. mg/g for NCBC, 3.97. mg/g for NZCBC and 6.08. mg/g for ACBC, respectively. Results of the kinetic and isotherm modeling studies revealed that the adsorption data fitted well with a pseudo-second order and Langmuir model. In among the tested bio-chars, the bio-char (ACBC) was largely equivalent to activated carbon: AC (9.97. mg/g) in terms of adsorption capacity. All results indicated that the bio-chars had higher adsorption capacity than some chars and activated carbons reported previously, and also that these bio-chars could be used successfully as low-cost adsorbents for the removal of chromium ions from aqueous solutions under the tested experimental conditions. © 2012 The Korean Society of Industrial and Engineering Chemistry.