Synthesis of the ketimine of chitosan and 4,6-diacetylresorcinol, and study of the catalase-like activity of its copper chelate

DEMETGÜL C.

Carbohydrate Polymers, vol.89, no.2, pp.354-361, 2012 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 89 Issue: 2
  • Publication Date: 2012
  • Doi Number: 10.1016/j.carbpol.2012.03.013
  • Journal Name: Carbohydrate Polymers
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.354-361
  • Keywords: 4,6-Diacetylresorcinol (DAR), Chitosan derivative, Copper (II) complex, Hydrogen peroxide decomposition, Ketimine
  • Hatay Mustafa Kemal University Affiliated: Yes

Abstract

In this study, a new chitosan derivative (ketimine) was synthesized by condensation of chitosan with 4,6-diacetylresorcinol (DAR) at heterogeneous medium. The ketimine derivative of chitosan (DAR-chitosan) was characterized by elemental (C, H, N), spectral (DR-UV-vis and FT-IR spectroscopy), structural (powder XRD), and morphological (SEM) analyses. The degree of substitution (DS) of DAR-chitosan was evaluated by elemental analysis and 13C CP-MAS NMR spectroscopy and found to be around 12%. The copper (II) metal complex of DAR-chitosan was prepared and characterized by FT-IR, DR-UV-vis and inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Thermal behaviors of the synthesized compounds were investigated by DSC and TG-DTG-DTA analysis. The catalytic activity of copper (II) complex of chitosan derivative (DAR-chitosan-Cu) was investigated on hydrogen peroxide decomposition. The copper chelate showed high efficiency (over 80%) towards the decomposition of hydrogen peroxide as heterogeneous catalyst. © 2012 Elsevier Ltd. All rights reserved.