Optimization of synthesis conditions of PbS thin films grown by chemical bath deposition using response surface methodology

YÜCEL E., YÜCEL Y., Beleli B.

Journal of Alloys and Compounds, vol.642, pp.63-69, 2015 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 642
  • Publication Date: 2015
  • Doi Number: 10.1016/j.jallcom.2015.03.267
  • Journal Name: Journal of Alloys and Compounds
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.63-69
  • Keywords: Chemical bath deposition, Optimization, PbS thin films, Response surface methodology
  • Hatay Mustafa Kemal University Affiliated: Yes

Abstract

In this study, PbS thin films were synthesized by chemical bath deposition (CBD) under different deposition parameters. Response surface methodology (RSM) was used to optimize synthesis parameters including amount of tri-sodium citrate (0.2-0.8 mL), deposition time (14-34 h) and deposition temperature (26.6-43.4 °C) for deposition of the films. 5-level-3-factor central composite design (CCD) was employed to evaluate effects of the deposition parameters on the response (optical band gap of the films). The significant level of both the main effects and the interaction are investigated by analysis of variance (ANOVA). The film structures were characterized by X-ray diffractometer (XRD). Morphological properties of the films were studied with a scanning electron microscopy (SEM). The optical properties of the films were investigated using a UV-visible spectrophotometer. The optimum amount of tri-sodium citrate, deposition time and deposition temperature were found to be 0.7 mL, 18.07 h and 30°C respectively. Under these conditions, the experimental band gap of PbS was 2.20 eV, which is quite good correlation with value (1.98 eV) predicted by the model.